Reaction between Phenylcyanate and N, N-Disubstituted Diphenyl Phosphinous Amide or Diphenyl Phosphorus Amide
نویسندگان
چکیده
منابع مشابه
P,P-Diphenyl-N-(1,1,2,2-tetraphenyl-1λ5-diphosphanylidene)phosphinous amide
The title compound, C(36)H(30)NP(3), a structural isomer of tris-(diphenyl-phosphino)amine, was unexpectedly isolated as the sole phospho-rus-containing product from the reaction of Mg[N(PPh(2))(2)](2)(THF)(2) (THF is tetra-hydro-furan) with CO(2). Its identity was confirmed by (31)P NMR spectroscopy and single-crystal X-ray diffraction. The geometry at the two P(III) atoms is trigonal pyramida...
متن کاملN,N-Bis(cyanomethyl)nitrous amide
In the title compound, C(4)H(4)N(4)O, both H atoms bonded to one methyl-ene C atom are involved in C-H⋯N hydrogen-bonding inter-actions; one of the inter-actions results in dimers of the title mol-ecule lying about inversion centers in R(2) (2)(12) motifs and the other forms chains of mol-ecules lying along the c axis.
متن کاملN,N′-Dimethyl-N,N′-diphenyl-3-oxapentanediamide
In the title compound, C(18)H(20)N(2)O(3), the two phenyl rings, adopt opposite orientations in the backbone and are oriented at a dihedral angle of 36.66 (3)°. In the crystal, inter-molecular C-H⋯O inter-actions link the mol-ecules into a three-dimensional network.
متن کاملN,P,P-Triisopropylphosphinic amide
The title compound, C(9)H(22)NOP, was obtained by slow diffusion of oxygen into a toluene solution of (i)Pr(2)PNH(i)Pr. In the crystal, an inter-molecular N-H⋯O hydrogen bond occurs.
متن کامل2,2-Diphenyl-N-(2,4,5-trichlorophenyl)acetamide
The asymmetric unit of the title compound, C(20)H(14)Cl(3)NO, consists of two independent mol-ecules. In one mol-ecule, the chlorinated benzene ring forms dihedral angles of 12.00 (9) and 77.04 (9)° with the phenyl rings. The dihedral angle between the phenyl rings is 80.37 (10)°. The corresponding dihedral angles for the other mol-ecule are 26.34 (10), 62.98 (10) and 88.47 (11)°, respectively....
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1969
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.72.11_2503